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Weak becomes strong: remarkable strength of C-H center dot center dot center dot pi hydrogen bond in the presence of O-H center dot center dot center dot O hydrogen bonds in the crystal stabilization

TitleWeak becomes strong: remarkable strength of C-H center dot center dot center dot pi hydrogen bond in the presence of O-H center dot center dot center dot O hydrogen bonds in the crystal stabilization
Publication TypeJournal Article
Year of Publication2013
AuthorsSureshan, KM, Gonnade, RG
JournalCrystEngComm
Volume15
Issue9
Pagination1676-1679
Date PublishedJAN
Type of ArticleArticle
ISSN1466-8033
Abstract

We report crystallographic evidence for the significance of C-H center dot center dot center dot pi hydrogen bonds in the crystal stabilization of 1,4-di-O-benzoyl-myo-inositol. The strength of this otherwise weak hydrogen bond matches with the strength of O-H center dot center dot center dot O hydrogen bonds.

DOI10.1039/c3ce26894b
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

3.858

Divison category: 
Center for Material Characterization (CMC)