Synthesis of pseudo-indoxyl derivatives via sequential Cu-catalyzed SNAr and Smalley cyclization

TitleSynthesis of pseudo-indoxyl derivatives via sequential Cu-catalyzed SNAr and Smalley cyclization
Publication TypeJournal Article
Year of Publication2013
AuthorsGoriya, Y, Ramana, CV
JournalChemical Communications
Volume49
Issue57
Pagination6376-6378
Date PublishedAPR
ISSN1359-7345
Abstract

ortho-Bromophenyl sec-alkyl/sec-alkenyl ketones, on reaction with sodium azide in the presence of copper salts, undergo sequential SNAr followed by Smalley cyclization to provide pseudo-indoxyl derivatives. Some of these pseudo-indoxyl derivatives exhibit interesting fluorescent properties and broad Stokes shifts.

DOI10.1039/c3cc41348a
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

6.718

Divison category: 
Organic Chemistry