Reaction of diaryl-1,2-diones with triphenylphosphine and diethyl azodicarboxylate leading to N, N-dicarboethoxy monohydrazones via a novel rearrangement

TitleReaction of diaryl-1,2-diones with triphenylphosphine and diethyl azodicarboxylate leading to N, N-dicarboethoxy monohydrazones via a novel rearrangement
Publication TypeJournal Article
Year of Publication2005
AuthorsNair, V, Biju, AT, Abhilash, KG, Menon, RS, Eringathodi, S
JournalOrganic Letters
Volume7
Issue11
Pagination2121–2123
Date PublishedMAY
Abstract

A mechanistically novel reaction of diaryl-1,2-diones with diethyl azodicarboxylate and triphenylphosphine to afford N,N-dicarboethoxy monohydrazones is described. The reaction proceeds via a nitrogen to nitrogen migration of a carboethoxy group.

DOI10.1021/ol050403+
Funding Agency

Council of Scientific & Industrial Research (CSIR) - India

Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

6.732

Divison category: 
Organic Chemistry