New synthetic approach to a [1.1.6] metapara cyclophane derivative via Suzuki-Miyaura cross-coupling and ring-closing metathesis

TitleNew synthetic approach to a [1.1.6] metapara cyclophane derivative via Suzuki-Miyaura cross-coupling and ring-closing metathesis
Publication TypeJournal Article
Year of Publication2005
AuthorsKotha, S, Mandal, K, Arora, KK, Pedireddi, R
JournalAdvanced Synthesis & Catalysis
Volume347
Issue9
Pagination1215-1218
Date PublishedJUL
ISSN1615-4150
KeywordsCyclophanes, olefin metathesis, Palladium, ruthenium, Suzuki-Miyaura cross-coupling
Abstract

The synthesis of a [1.1.6] metapara cyclophane derivative, 1,5(1,4),3(1,3)-tribenzenacycloun-decaphan-8-ene-6,11-dione, has been achieved via the Suzuki-Miyaura cross-coupling of alpha,alpha'-dibromo-m-xylene with an arylboronic acid derivative followed by an allylation and ring-closing metathesis reaction sequence.

DOI10.1002/adsc.200404373
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

6.453

Divison category: 
Organic Chemistry