Mechanistic approach for expeditious and solvent-free synthesis of alpha-hydroxy phosphonates using potassium phosphate as catalyst

TitleMechanistic approach for expeditious and solvent-free synthesis of alpha-hydroxy phosphonates using potassium phosphate as catalyst
Publication TypeJournal Article
Year of Publication2013
AuthorsKulkarni, MA, Lad, UP, Desai, UV, Mitragotri, SD, Wadgaonkar, PP
JournalComptes Rendus Chimie
Volume16
Issue2
Pagination148-152
Date PublishedFEB
ISSN1631-0748
Keywordsalpha-hydroxy phosphonates, Hydrophosphylation, Potassium phosphate, Solvent-free
Abstract

An extremely simple, high yielding, highly rapid and solvent-free protocol has been described for hydrophosphylation of aldehydes using potassium phosphate as catalyst. Easy commercial availability of the reusable catalyst, operational simplicity at ambient temperature and avoidance of conventional work-up as well as purification procedure makes this solvent-free protocol a near-ideal synthesis. (C) 2012 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.

DOI10.1016/j.crci.2012.10.009
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

1.49

Divison category: 
Organic Chemistry
Polymer Science & Engineering