Highly chemoselective catalytic system for hydrogenation of diketones to ketols: an environmentally benevolent system

TitleHighly chemoselective catalytic system for hydrogenation of diketones to ketols: an environmentally benevolent system
Publication TypeJournal Article
Year of Publication2008
AuthorsDeshmukh, AA, Kinage, AK, Kumar, R
JournalCatalysis Letters
Volume120
Issue3-4
Pagination257-260
Date PublishedJAN
Type of ArticleArticle
ISSN1011-372X
KeywordsChemoselective, dione, Hydrogenation, ketol, ruthenium phenanthroline, Water
Abstract

Ru(Phen)(2)Cl-2 [Phen = Phenanthroline] anchored in organo-functionalized MCM-41 [Ru(Phen)(2)Cl-NH-MCM-41] efficiently catalyzes highly chemoselective hydrogenation of diketones to ketols (Sel. similar to 99%) under environmentally benign tri-phasic (solid-liquid-liquid) reaction condition in aqueous medium.

DOI10.1007/s10562-007-9278-3
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

2.294

Divison category: 
Catalysis and Inorganic Chemistry