Highly active recyclable SBA-15-EDTA-Pd catalyst for Mizoroki-Heck, Stille and Kumada C-C coupling reactions

TitleHighly active recyclable SBA-15-EDTA-Pd catalyst for Mizoroki-Heck, Stille and Kumada C-C coupling reactions
Publication TypeJournal Article
Year of Publication2017
AuthorsRathod, J, Sharma, P, Pandey, P, Singh, AP, Kumar, P
JournalJournal of Porous Materials
Volume24
Issue4
Pagination837-846
Date PublishedAUG
Type of ArticleArticle
Abstract

Highly efficient SBA-15-EDTA-Pd(11) heterogeneous catalyst was synthesized by covalent anchoring Pd-EDTA complex over organo-modified surface of SBA-15. SBA-15-EDTA-Pd(11) catalyst was found to exhibit excellent catalytic activity in appreciable yield for Heck, Stille and Kumada cross-coupling reactions. Catalytic system exhibited excellent activity for completion of reaction, isolation, Pd loading (0.87 mmol%) and yields of products as compared to earlier reported heterogeneous supported Pd catalysts. Covalently anchored heterogeneous SBA-15-EDTA-Pd(11) catalyst can be recycled for more than five times without noticeable loss in activity and selectivity.

DOI10.1007/s10934-016-0323-8
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

1.385

Divison category: 
Catalysis and Inorganic Chemistry
Organic Chemistry