Formal synthesis of (+)-didemniserinolipid B employing a Pd-mediated 6-endo selective alkynediol cycloisomerization

TitleFormal synthesis of (+)-didemniserinolipid B employing a Pd-mediated 6-endo selective alkynediol cycloisomerization
Publication TypeJournal Article
Year of Publication2009
AuthorsRamana, CV, Induvadana, B
JournalTetrahedron Letters
Volume50
Issue3
Pagination271-273
Date PublishedJAN
ISSN0040-4039
KeywordsAlkynol cycloisomerization, Bridged bicyclic ketal, Didemniserinolipid, Yamaguchi oxirane alkyne coupling, Zipper reaction
Abstract

Herein, we describe a concise assembly of central 6,8-dioxabicyclo[3,2,1]octane core of didemniserino-lipid by employing a Pd-mediated alkynediol cycloisomerization and a formal total synthesis of didemniserinolipid (C) 2008 Elsevier Ltd. All rights reserved.

DOI10.1016/j.tetlet.2008.10.137
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

2.618

Divison category: 
Organic Chemistry