Efficient higher-order cycloaddition reactions of 8,8-dicyanoheptafulvenes with dienes

TitleEfficient higher-order cycloaddition reactions of 8,8-dicyanoheptafulvenes with dienes
Publication TypeJournal Article
Year of Publication2007
AuthorsNair, V, K. Abhilash, G, Biju, AT, Eringathodi, S
JournalSynthesis-Stuttgart
Issue12
Pagination1833-1836
Date PublishedJUN
Type of ArticleArticle
Keywordscycloadditions - bicyclic compounds - polycycles - di­cyanoheptafulvene - tetrahydroazulenes
Abstract

The cycloaddition reactions of 8,8-dicyanoheptafulvene with electron-rich dienes afforded the higher order cycloaddition products in excellent yields. With cyclic dienes as well as dimeth­oxybutadiene the [8+2] adducts were obtained exclusively. With methyl- and dimethylbutadienes the [6+4] adducts were the only products isolated.

DOI10.1055/s-2007-983711
Funding Agency

Council of Scientific & Industrial Research (CSIR) - India

Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

2.652

Divison category: 
Organic Chemistry