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2,5-dioxido-1,4-benzoquinonediimine (H2L2-), a hydrogen-bonding noninnocent bridging ligand related to aminated topaquinone: different oxidation state distributions in complexes [(bpy)(2)Ru(2)(mu-H2L)](n) (n=0,+,2+,3+,4+) and [(acac)(2)Ru(2)(mu-H2L)]

Title2,5-dioxido-1,4-benzoquinonediimine (H2L2-), a hydrogen-bonding noninnocent bridging ligand related to aminated topaquinone: different oxidation state distributions in complexes [(bpy)(2)Ru(2)(mu-H2L)](n) (n=0,+,2+,3+,4+) and [(acac)(2)Ru(2)(mu-H2L)]
Publication TypeJournal Article
Year of Publication2005
AuthorsKar, S, Sarkar, B, Ghumaan, S, Janardanan, D, van Slageren, J, Fiedler, J, Puranik, VG, Sunoj, RB, Kaim, W, Lahiri, GKumar
JournalChemistry - a European Journal
Volume11
Issue17
Pagination4901-4911
Date PublishedAUG
Type of ArticleArticle
ISSN0947-6539
Keywordsbridging ligands, Density functional calculations, EPR spectroscopy, N, O ligands, ruthenium
Abstract

{The symmetrically dinuclear title compounds were isolated as diamagnetic [(bpy)(2)Ru(mu-H2L)Ru(bpy)(2)]- (ClO4)(2) (1-(ClO4)(2)) and as paramagnetic [(acac)(2)Ru(mu-H2L)Ru(acac)(2)] (2) complexes (bpy = 2,2'-bipyridine; acac(-) -

DOI10.1002/chem.2005.00202
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

5.771

Divison category: 
Center for Material Characterization (CMC)
Physical and Materials Chemistry