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2-Aroylindoles from o-bromochalcones via Cu(I)-catalyzed SNAr with an azide and intramolecular nitrene C-H insertion

Title2-Aroylindoles from o-bromochalcones via Cu(I)-catalyzed SNAr with an azide and intramolecular nitrene C-H insertion
Publication TypeJournal Article
Year of Publication2014
AuthorsGoriya, Y, Ramana, CV
JournalChemical Communications
Volume50
Issue58
Pagination7790-7792
Date PublishedMay
Type of ArticleArticle
ISSN1359-7345
Abstract

A simple procedure for the synthesis of 2-aroylindole derivatives comprising a one-pot CuI-catalyzed SNAr reaction of o-bromochalconeswith sodium azide and subsequent intramolecular cyclization through nitrene C-H insertion has been developed. This protocol is also applicablewith the 2'-bromocinnamates giving the indole-2-carboxylates.

DOI10.1039/c4cc02501f
Type of Journal (Indian or Foreign)

Foreign

Impact Factor (IF)

6.567

Divison category: 
Organic Chemistry